FR 3223 then LS 957 at Manchester
Brussels Charleroi → Manchester → Alicante
Timetable, Manchester time
19:40FR 3223 from Brussels Charleroi at the gate
17:15LS 957 to Alicante leaves the gate
21 h 35 apart on the timetable, overnight
LS 957 leaves 21 h 35 after FR 3223 arrives on the timetable: more than half a day, so not a connection we count.