FR 4003 then FR 6596 at Manchester
Vienna → Manchester → Barcelona
Timetable, Manchester time
07:35FR 4003 from Vienna at the gate
06:30FR 6596 to Barcelona leaves the gate
22 h 55 apart on the timetable, overnight
FR 6596 leaves 22 h 55 after FR 4003 arrives on the timetable: more than half a day, so not a connection we count.