FR 5270 then FR 4052 at Manchester
Barcelona → Manchester → Faro
Timetable, Manchester time
11:55FR 5270 from Barcelona at the gate
09:40FR 4052 to Faro leaves the gate
21 h 45 apart on the timetable, overnight
FR 4052 leaves 21 h 45 after FR 5270 arrives on the timetable: more than half a day, so not a connection we count.