FR 5477 then FR 6814 at Manchester
Verona → Manchester → Madrid
Timetable, Manchester time
13:55FR 5477 from Verona at the gate
12:40FR 6814 to Madrid leaves the gate
22 h 45 apart on the timetable, overnight
FR 6814 leaves 22 h 45 after FR 5477 arrives on the timetable: more than half a day, so not a connection we count.