FR 614 then FR 641 at Manchester
Brussels Charleroi → Manchester → Valencia
Timetable, Manchester time
19:15FR 614 from Brussels Charleroi at the gate
17:40FR 641 to Valencia leaves the gate
22 h 25 apart on the timetable, overnight
FR 641 leaves 22 h 25 after FR 614 arrives on the timetable: more than half a day, so not a connection we count.