FR 640 then FR 2242 at Manchester
Valencia → Manchester → Bologna
Timetable, Manchester time
14:55FR 640 from Valencia at the gate
12:50FR 2242 to Bologna leaves the gate
21 h 55 apart on the timetable, overnight
FR 2242 leaves 21 h 55 after FR 640 arrives on the timetable: more than half a day, so not a connection we count.