FR 6597 then FR 4076 at Manchester
Barcelona → Manchester → Alicante
Timetable, Manchester time
19:50FR 6597 from Barcelona at the gate
09:50FR 4076 to Alicante leaves the gate
14 h apart on the timetable, overnight
FR 4076 leaves 14 h after FR 6597 arrives on the timetable: more than half a day, so not a connection we count.