FR 6597 then KL 1030 at Manchester
Barcelona → Manchester → Amsterdam
Timetable, Manchester time
19:50FR 6597 from Barcelona at the gate
09:05KL 1030 to Amsterdam leaves the gate
13 h 15 apart on the timetable, overnight
KL 1030 leaves 13 h 15 after FR 6597 arrives on the timetable: more than half a day, so not a connection we count.