FR 6631 then FR 6814 at Manchester
Cologne → Manchester → Madrid
Timetable, Manchester time
21:15FR 6631 from Cologne at the gate
20:20FR 6814 to Madrid leaves the gate
23 h 05 apart on the timetable, overnight
FR 6814 leaves 23 h 05 after FR 6631 arrives on the timetable: more than half a day, so not a connection we count.