FR 6966 then FR 4007 at Manchester
Valencia → Manchester → Alicante
Timetable, Manchester time
00:55FR 6966 from Valencia at the gate
16:55FR 4007 to Alicante leaves the gate
16 h apart on the timetable
FR 4007 leaves 16 h after FR 6966 arrives on the timetable: more than half a day, so not a connection we count.