FR 6968 then FR 6596 at Manchester
Copenhagen → Manchester → Barcelona
Timetable, Manchester time
12:05FR 6968 from Copenhagen at the gate
06:30FR 6596 to Barcelona leaves the gate
18 h 25 apart on the timetable, overnight
FR 6596 leaves 18 h 25 after FR 6968 arrives on the timetable: more than half a day, so not a connection we count.