LS 804 then FR 8716 at Manchester
Barcelona → Manchester → Madrid
Timetable, Manchester time
15:30LS 804 from Barcelona at the gate
13:10FR 8716 to Madrid leaves the gate
21 h 40 apart on the timetable, overnight
FR 8716 leaves 21 h 40 after LS 804 arrives on the timetable: more than half a day, so not a connection we count.