LS 988 then FR 5624 at Manchester
Rome → Manchester → Pisa
Timetable, Manchester time
21:25LS 988 from Rome at the gate
16:30FR 5624 to Pisa leaves the gate
19 h 05 apart on the timetable, overnight
FR 5624 leaves 19 h 05 after LS 988 arrives on the timetable: more than half a day, so not a connection we count.