U2 2002 then FR 6814 at Manchester
Barcelona → Manchester → Madrid
Timetable, Manchester time
12:55U2 2002 from Barcelona at the gate
12:50FR 6814 to Madrid leaves the gate
23 h 55 apart on the timetable, overnight
FR 6814 leaves 23 h 55 after U2 2002 arrives on the timetable: more than half a day, so not a connection we count.