U2 2202 then FR 6814 at Manchester
Berlin → Manchester → Madrid
Timetable, Manchester time
22:55U2 2202 from Berlin at the gate
12:50FR 6814 to Madrid leaves the gate
13 h 55 apart on the timetable, overnight
FR 6814 leaves 13 h 55 after U2 2202 arrives on the timetable: more than half a day, so not a connection we count.