VY 7754 then FR 6814 at Manchester
Barcelona → Manchester → Madrid
Timetable, Manchester time
12:55VY 7754 from Barcelona at the gate
08:15FR 6814 to Madrid leaves the gate
19 h 20 apart on the timetable, overnight
FR 6814 leaves 19 h 20 after VY 7754 arrives on the timetable: more than half a day, so not a connection we count.