AA 1591 then VS 118 at Miami
New Orleans → Miami → London
Timetable, Miami time
11:01AA 1591 from New Orleans at the gate
23:35VS 118 to London leaves the gate
12 h 34 apart on the timetable
VS 118 leaves 12 h 34 after AA 1591 arrives on the timetable: more than half a day, so not a connection we count.