EC 6103 then EN 1924 at Munich
Rome → Munich → Venezia
Timetable, Munich time
14:05EC 6103 from Rome at the gate
11:30EN 1924 to Venezia leaves the gate
21 h 25 apart on the timetable, overnight
EN 1924 leaves 21 h 25 after EC 6103 arrives on the timetable: more than half a day, so not a connection we count.