EN 1925 then LH 1914 at Munich
Venezia → Munich → Palermo
Timetable, Munich time
14:10EN 1925 from Venezia at the gate
09:20LH 1914 to Palermo leaves the gate
19 h 10 apart on the timetable, overnight
LH 1914 leaves 19 h 10 after EN 1925 arrives on the timetable: more than half a day, so not a connection we count.