SN 2645 then LH 1914 at Munich
Brussels → Munich → Palermo
Timetable, Munich time
14:05SN 2645 from Brussels at the gate
09:20LH 1914 to Palermo leaves the gate
19 h 15 apart on the timetable, overnight
LH 1914 leaves 19 h 15 after SN 2645 arrives on the timetable: more than half a day, so not a connection we count.