VL 1809 then LH 504 at Munich
Barcelona → Munich → São Paulo
Timetable, Munich time
11:10VL 1809 from Barcelona at the gate
10:50LH 504 to São Paulo leaves the gate
23 h 40 apart on the timetable, overnight
LH 504 leaves 23 h 40 after VL 1809 arrives on the timetable: more than half a day, so not a connection we count.