OO 6058 then AA 559 at O'Hare
Sioux City → Chicago → Puerto Vallarta
Timetable, Chicago time
10:13OO 6058 from Sioux City at the gate
08:05AA 559 to Puerto Vallarta leaves the gate
21 h 52 apart on the timetable, overnight
AA 559 leaves 21 h 52 after OO 6058 arrives on the timetable: more than half a day, so not a connection we count.