UA 5064 then CV 32 at O'Hare
Decatur → Chicago → Luxembourg
Timetable, Chicago time
20:25UA 5064 from Decatur at the gate
18:40CV 32 to Luxembourg leaves the gate
22 h 15 apart on the timetable, overnight
CV 32 leaves 22 h 15 after UA 5064 arrives on the timetable: more than half a day, so not a connection we count.