UA 5195 then AA 1012 at O'Hare
Macon → Chicago → Washington National
Timetable, Chicago time
14:30UA 5195 from Macon at the gate
08:45AA 1012 to Washington National leaves the gate
18 h 15 apart on the timetable, overnight
AA 1012 leaves 18 h 15 after UA 5195 arrives on the timetable: more than half a day, so not a connection we count.