UA 5466 then CV 12 at O'Hare
Peoria → Chicago → Luxembourg
Timetable, Chicago time
19:00UA 5466 from Peoria at the gate
14:55CV 12 to Luxembourg leaves the gate
19 h 55 apart on the timetable, overnight
CV 12 leaves 19 h 55 after UA 5466 arrives on the timetable: more than half a day, so not a connection we count.