AA 5333 then UA 225 at Philadelphia
Pensacola → Philadelphia → San Francisco
Timetable, Philadelphia time
16:50AA 5333 from Pensacola at the gate
16:38UA 225 to San Francisco leaves the gate
23 h 48 apart on the timetable, overnight
UA 225 leaves 23 h 48 after AA 5333 arrives on the timetable: more than half a day, so not a connection we count.