WN 4820 then WN 3523 at Phoenix
Pittsburgh → Phoenix → Santa Ana
Timetable, Phoenix time
08:50WN 4820 from Pittsburgh at the gate
22:00WN 3523 to Santa Ana leaves the gate
13 h 10 apart on the timetable
WN 3523 leaves 13 h 10 after WN 4820 arrives on the timetable: more than half a day, so not a connection we count.