FR 690 then FR 214 at Vienna
Madrid → Vienna → Milan
Timetable, Vienna time
19:40FR 690 from Madrid at the gate
19:25FR 214 to Milan leaves the gate
23 h 45 apart on the timetable, overnight
FR 214 leaves 23 h 45 after FR 690 arrives on the timetable: more than half a day, so not a connection we count.