AA 5667 then AA 5030 at Toronto Pearson
Washington National → Toronto → Charlotte
Timetable, Toronto time
16:34AA 5667 from Washington National at the gate
15:49AA 5030 to Charlotte leaves the gate
23 h 15 apart on the timetable, overnight
AA 5030 leaves 23 h 15 after AA 5667 arrives on the timetable: more than half a day, so not a connection we count.