AC 118 then AC 92 at Toronto Pearson
Vancouver → Toronto → Santiago de Chile
Timetable, Toronto time
23:59AC 118 from Vancouver at the gate
23:35AC 92 to Santiago de Chile leaves the gate
23 h 36 apart on the timetable, overnight
AC 92 leaves 23 h 36 after AC 118 arrives on the timetable: more than half a day, so not a connection we count.