AC 1803 then AC 462 at Toronto Pearson
Kingston → Toronto → Ottawa
Timetable, Toronto time
20:25AC 1803 from Kingston at the gate
18:35AC 462 to Ottawa leaves the gate
22 h 10 apart on the timetable, overnight
AC 462 leaves 22 h 10 after AC 1803 arrives on the timetable: more than half a day, so not a connection we count.