AC 1919 then AC 92 at Toronto Pearson
Ottawa → Toronto → Santiago de Chile
Timetable, Toronto time
10:28AC 1919 from Ottawa at the gate
23:35AC 92 to Santiago de Chile leaves the gate
13 h 07 apart on the timetable
AC 92 leaves 13 h 07 after AC 1919 arrives on the timetable: more than half a day, so not a connection we count.