AC 2061 then AC 125 at Toronto Pearson
St. John's → Toronto → Vancouver
Timetable, Toronto time
07:20AC 2061 from St. John's at the gate
20:20AC 125 to Vancouver leaves the gate
13 h apart on the timetable
AC 125 leaves 13 h after AC 2061 arrives on the timetable: more than half a day, so not a connection we count.