PD 772 then AC 2078 at Toronto Pearson
Puerto Vallarta → Toronto → St. John's
Timetable, Toronto time
23:57PD 772 from Puerto Vallarta at the gate
21:00AC 2078 to St. John's leaves the gate
21 h 03 apart on the timetable, overnight
AC 2078 leaves 21 h 03 after PD 772 arrives on the timetable: more than half a day, so not a connection we count.