WS 2737 then AC 90 at Toronto Pearson
Punta Cana → Toronto → São Paulo
Timetable, Toronto time
21:35WS 2737 from Punta Cana at the gate
21:00AC 90 to São Paulo leaves the gate
23 h 25 apart on the timetable, overnight
AC 90 leaves 23 h 25 after WS 2737 arrives on the timetable: more than half a day, so not a connection we count.